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Thursday, October 22, 2009
Things That You Can Do In the Garden
Month of November has also known as a good month for gardening. You might one of people who enjoy gardening and attracted to always make your garden in beautiful look, but somehow you do not have much time previously. Next month can be your finest time to do things on your garden and if you are confused about what things that you can do in the garden, the information below can be your inspiration.
Planting trees or fruits are fun you can start with remove the top layer to form a small channel and then dig over the soil at the bottom of the channel adding compost. Repeat and fill the first channel with the top soil from the second, the soil from the fist channel then plugs in the last channel. Alternatively, you can cut away any dead trail in fruit trees and clear areas of your garden and make sure that young trees well maintained with stakes to prevent from strong winter winds.
Other options that you can plant in your garden are vegetables like potatoes or garlic offering good opportunity in November. This information is one of articles that you can read easily through online articles website, there are plenty of articles, which you can read this site such as topics about education, life style, home furniture, gadget, technology, health, gardening, and many more articles. Consider this website as your best place to search for alternative, resources or recommendation in life issues.
Planting trees or fruits are fun you can start with remove the top layer to form a small channel and then dig over the soil at the bottom of the channel adding compost. Repeat and fill the first channel with the top soil from the second, the soil from the fist channel then plugs in the last channel. Alternatively, you can cut away any dead trail in fruit trees and clear areas of your garden and make sure that young trees well maintained with stakes to prevent from strong winter winds.
Other options that you can plant in your garden are vegetables like potatoes or garlic offering good opportunity in November. This information is one of articles that you can read easily through online articles website, there are plenty of articles, which you can read this site such as topics about education, life style, home furniture, gadget, technology, health, gardening, and many more articles. Consider this website as your best place to search for alternative, resources or recommendation in life issues.
Wednesday, October 21, 2009
Trigonometry for Dummies
This is a doublet of doublets. If you move one doublet towards the other, for example by increasing the smaller J, the central peaks will coalesce into a single peak of double intensity (the algebraic sum of the central peaks).
A triplet is a special case of doublet of doublets (the Js are identical).
Another doublet of doublets. This time the smaller coupling is anti-phase.
If we increase the small J, we'll see another algebraic addition.
This is a triplet. Right?
Tuesday, October 20, 2009
NMR for Dummies
Here is where the real fun begins. I was not joking with my previous post. You can really do these things at home. The simple instructions are available on another site, and they are illustrated. After completing the tutorial (it takes 5 minutes in total) a working application will remain in your hard disc, and you will be free to apply the same treatment to your own spectra.
iNMR has always been available as a free download (since 2005). Access is unlimited and the program never expires. Other specialized simulation modules are included to cover most of the needs of an advanced spectroscopist (the few exceptions are motivated by the fact that other needs were already covered by existing freeware).
My blog is three years old. Half of the comments have been dedicated to a single post, which is clearly (and purposely) the least representative of the blog. When people find something useful (and this is certainly the case today) and free, they don't comment.
If you are not going to comment, I will comment by myself.
COMMENT: although it's a serious work, although it contains a lot of maths (and maybe just for this reason) it's funny too.
iNMR has always been available as a free download (since 2005). Access is unlimited and the program never expires. Other specialized simulation modules are included to cover most of the needs of an advanced spectroscopist (the few exceptions are motivated by the fact that other needs were already covered by existing freeware).
My blog is three years old. Half of the comments have been dedicated to a single post, which is clearly (and purposely) the least representative of the blog. When people find something useful (and this is certainly the case today) and free, they don't comment.
If you are not going to comment, I will comment by myself.
COMMENT: although it's a serious work, although it contains a lot of maths (and maybe just for this reason) it's funny too.
Friday, October 16, 2009
Try this at home
Returning to the DQF-COSY of taxole, I have found this challenge:
I couldn't tell which kind of multiplet it was. I have extracted the section corresponding to the red line and moved it into my novel simulator. Then I have introduced 3 couplings and pushed the "Fit" button.
That's all. The goodness of the fit is convincing. It is a doublet of doublets of doublets and the Js are: 14.7, 6.4 and 9.9 Hz. The latter corresponds to an antiphase coupling. Not only I know which kind of multiplet it is, I have also measured the Js!
You might feel it's funny, I find it amazing, perhaps somebody will say it is useful. "The coupling constants were extracted from the DQF-COSY by the blogger's simulator".
I couldn't tell which kind of multiplet it was. I have extracted the section corresponding to the red line and moved it into my novel simulator. Then I have introduced 3 couplings and pushed the "Fit" button.
That's all. The goodness of the fit is convincing. It is a doublet of doublets of doublets and the Js are: 14.7, 6.4 and 9.9 Hz. The latter corresponds to an antiphase coupling. Not only I know which kind of multiplet it is, I have also measured the Js!
You might feel it's funny, I find it amazing, perhaps somebody will say it is useful. "The coupling constants were extracted from the DQF-COSY by the blogger's simulator".
Digitization
I am continuing my explorations on board of my new multiplet simulator. It has been easy to simulate an asymmetric doublet. Here the asymmetry is only apparent and is due to the limited digitization.
As explained yesterday, the black line belongs to an experimental 2-D spectrum (today I have chosen a TOCSY), the red line is a theoretical doublet acquired and processed under the same conditions.
My simulator allows me to change the frequency by dragging the blue label at the bottom.
In this way the coupling remains constant. It turns out that my spectrum was a middle-range case. With a slight increase of the chemical shift I can obtain a symmetric doublet, or even a singlet!
As explained yesterday, the black line belongs to an experimental 2-D spectrum (today I have chosen a TOCSY), the red line is a theoretical doublet acquired and processed under the same conditions.
My simulator allows me to change the frequency by dragging the blue label at the bottom.
In this way the coupling remains constant. It turns out that my spectrum was a middle-range case. With a slight increase of the chemical shift I can obtain a symmetric doublet, or even a singlet!
Thursday, October 15, 2009
Copy Watch
Designer watches have been reigning over the hearts of the watch lovers for a long time now. The marvelous designs and unparalleled sophistication f the designer watches make them the most revered watches on the planet. The watch designs have been endowed with timeless elegance. The traditional excellence and the inventive genius of the watch designers combine in these watches, each watch giving a new dimension to horology. Prestigious designer and luxury watches serve more purposes than mere time keeping. They serve as the ultimate status symbol. These beautiful timepieces are often worn as accessory or a piece of jewelry.
The timepieces offered by the prestigious watch brands are often so expensive that it is almost impossible to buy them without giving a fatal blow to ones savings. For those who do not wish to spend a fortune over a watch, the replicas present a smarter option. The designer watch replicas are high quality copy watches with all the high-end features of the authentic timepieces. The copy watch is a perfect clone of the authentic designer watch. Apart from looking identical to the original, it also gives a similar feel and satisfaction. The fully functional and highly accurate copy watch comes for a price much lower than that of the authentic designer watch.
The making of copy watches is strictly regulated to ensure that only the best quality watches are produced. Equipped with high quality mechanical or quartz movement, the watches are functional and dependable. Every copy watch is decorated and assembled with hand. All the copy watch components are made up of good quality material. All the watch features are kept identical to the original. The watches thus produced are exact look-alikes of the authentic designer watches.
The timepieces offered by the prestigious watch brands are often so expensive that it is almost impossible to buy them without giving a fatal blow to ones savings. For those who do not wish to spend a fortune over a watch, the replicas present a smarter option. The designer watch replicas are high quality copy watches with all the high-end features of the authentic timepieces. The copy watch is a perfect clone of the authentic designer watch. Apart from looking identical to the original, it also gives a similar feel and satisfaction. The fully functional and highly accurate copy watch comes for a price much lower than that of the authentic designer watch.
The making of copy watches is strictly regulated to ensure that only the best quality watches are produced. Equipped with high quality mechanical or quartz movement, the watches are functional and dependable. Every copy watch is decorated and assembled with hand. All the copy watch components are made up of good quality material. All the watch features are kept identical to the original. The watches thus produced are exact look-alikes of the authentic designer watches.
